Use of the electrochromic behaviour of lanthanide phthalocyanine films for nicotinamide adenine dinucleotide detection.
Identifieur interne : 002083 ( Main/Exploration ); précédent : 002082; suivant : 002084Use of the electrochromic behaviour of lanthanide phthalocyanine films for nicotinamide adenine dinucleotide detection.
Auteurs : RBID : pubmed:17971319English descriptors
- KwdEn :
- MESH :
- chemical , analysis : NAD.
- chemical , chemistry : Indoles, Lanthanoid Series Elements, Tin Compounds.
- methods : Electrochemistry.
- Electrodes, Membranes, Artificial, Oxidation-Reduction.
Abstract
Electrochromic properties of spun films of bis[octakis(hexylthio)phthalocyaninato] dysprosium(III) were investigated for determining nicotinamide adenine dinucleotide hydride (NADH) in water solutions. A spin-coated film deposited on indium tin oxide electrode displays only one redox couple (at E1/2=0.78V). The films of [(C6H13S)8Pc]2Dy were modified chemically or electrochemically for the detection of reduced NADH in water solution. The modified film in the oxidized ([(C6H13S)8Pc]2Dy)+ form is believed to be reduced to its neutral form on interaction with NADH.
DOI: 10.1098/rsif.2007.1241
PubMed: 17971319
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Le document en format XML
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<author><name sortKey="Basova, T" uniqKey="Basova T">T Basova</name>
<affiliation wicri:level="1"><nlm:affiliation>Institute of Inorganic Chemistry, Lavrentiev Prospect 3, Novosibirsk 630090, Russia. tbasova@mail.ru</nlm:affiliation>
<country xml:lang="fr">Russie</country>
<wicri:regionArea>Institute of Inorganic Chemistry, Lavrentiev Prospect 3, Novosibirsk 630090</wicri:regionArea>
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<author><name sortKey="Jushina, I" uniqKey="Jushina I">I Jushina</name>
</author>
<author><name sortKey="G Rek, A G" uniqKey="G Rek A">A G Gürek</name>
</author>
<author><name sortKey="Ahsen, V" uniqKey="Ahsen V">V Ahsen</name>
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<author><name sortKey="Ray, A K" uniqKey="Ray A">A K Ray</name>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Electrochemistry (methods)</term>
<term>Electrodes</term>
<term>Indoles (chemistry)</term>
<term>Lanthanoid Series Elements (chemistry)</term>
<term>Membranes, Artificial</term>
<term>NAD (analysis)</term>
<term>Oxidation-Reduction</term>
<term>Tin Compounds (chemistry)</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>NAD</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Indoles</term>
<term>Lanthanoid Series Elements</term>
<term>Tin Compounds</term>
</keywords>
<keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Electrochemistry</term>
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<front><div type="abstract" xml:lang="en">Electrochromic properties of spun films of bis[octakis(hexylthio)phthalocyaninato] dysprosium(III) were investigated for determining nicotinamide adenine dinucleotide hydride (NADH) in water solutions. A spin-coated film deposited on indium tin oxide electrode displays only one redox couple (at E1/2=0.78V). The films of [(C6H13S)8Pc]2Dy were modified chemically or electrochemically for the detection of reduced NADH in water solution. The modified film in the oxidized ([(C6H13S)8Pc]2Dy)+ form is believed to be reduced to its neutral form on interaction with NADH.</div>
</front>
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<DateRevised><Year>2013</Year>
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<Issue>24</Issue>
<PubDate><Year>2008</Year>
<Month>Jul</Month>
<Day>6</Day>
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<Title>Journal of the Royal Society, Interface / the Royal Society</Title>
<ISOAbbreviation>J R Soc Interface</ISOAbbreviation>
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<ArticleTitle>Use of the electrochromic behaviour of lanthanide phthalocyanine films for nicotinamide adenine dinucleotide detection.</ArticleTitle>
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<Abstract><AbstractText>Electrochromic properties of spun films of bis[octakis(hexylthio)phthalocyaninato] dysprosium(III) were investigated for determining nicotinamide adenine dinucleotide hydride (NADH) in water solutions. A spin-coated film deposited on indium tin oxide electrode displays only one redox couple (at E1/2=0.78V). The films of [(C6H13S)8Pc]2Dy were modified chemically or electrochemically for the detection of reduced NADH in water solution. The modified film in the oxidized ([(C6H13S)8Pc]2Dy)+ form is believed to be reduced to its neutral form on interaction with NADH.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Basova</LastName>
<ForeName>T</ForeName>
<Initials>T</Initials>
<Affiliation>Institute of Inorganic Chemistry, Lavrentiev Prospect 3, Novosibirsk 630090, Russia. tbasova@mail.ru</Affiliation>
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<Chemical><RegistryNumber>574-93-6</RegistryNumber>
<NameOfSubstance>phthalocyanine</NameOfSubstance>
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<Chemical><RegistryNumber>71243-84-0</RegistryNumber>
<NameOfSubstance>indium tin oxide</NameOfSubstance>
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<CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>Curr Opin Cell Biol. 2003 Apr;15(2):241-6</RefSource>
<PMID Version="1">12648681</PMID>
</CommentsCorrections>
<CommentsCorrections RefType="Cites"><RefSource>Adv Colloid Interface Sci. 2005 Nov 30;116(1-3):1-11</RefSource>
<PMID Version="1">16083837</PMID>
</CommentsCorrections>
<CommentsCorrections RefType="Cites"><RefSource>Analyst. 2005 Sep;130(9):1232-9</RefSource>
<PMID Version="1">16096667</PMID>
</CommentsCorrections>
<CommentsCorrections RefType="Cites"><RefSource>J Am Chem Soc. 2003 Apr 9;125(14):4014-5</RefSource>
<PMID Version="1">12670199</PMID>
</CommentsCorrections>
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</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N">Oxidation-Reduction</DescriptorName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N">Tin Compounds</DescriptorName>
<QualifierName MajorTopicYN="Y">chemistry</QualifierName>
</MeshHeading>
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