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Use of the electrochromic behaviour of lanthanide phthalocyanine films for nicotinamide adenine dinucleotide detection.

Identifieur interne : 002083 ( Main/Exploration ); précédent : 002082; suivant : 002084

Use of the electrochromic behaviour of lanthanide phthalocyanine films for nicotinamide adenine dinucleotide detection.

Auteurs : RBID : pubmed:17971319

English descriptors

Abstract

Electrochromic properties of spun films of bis[octakis(hexylthio)phthalocyaninato] dysprosium(III) were investigated for determining nicotinamide adenine dinucleotide hydride (NADH) in water solutions. A spin-coated film deposited on indium tin oxide electrode displays only one redox couple (at E1/2=0.78V). The films of [(C6H13S)8Pc]2Dy were modified chemically or electrochemically for the detection of reduced NADH in water solution. The modified film in the oxidized ([(C6H13S)8Pc]2Dy)+ form is believed to be reduced to its neutral form on interaction with NADH.

DOI: 10.1098/rsif.2007.1241
PubMed: 17971319

Links toward previous steps (curation, corpus...)


Le document en format XML

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<name sortKey="Basova, T" uniqKey="Basova T">T Basova</name>
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<nlm:affiliation>Institute of Inorganic Chemistry, Lavrentiev Prospect 3, Novosibirsk 630090, Russia. tbasova@mail.ru</nlm:affiliation>
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<name sortKey="Ahsen, V" uniqKey="Ahsen V">V Ahsen</name>
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<term>Membranes, Artificial</term>
<term>NAD (analysis)</term>
<term>Oxidation-Reduction</term>
<term>Tin Compounds (chemistry)</term>
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<div type="abstract" xml:lang="en">Electrochromic properties of spun films of bis[octakis(hexylthio)phthalocyaninato] dysprosium(III) were investigated for determining nicotinamide adenine dinucleotide hydride (NADH) in water solutions. A spin-coated film deposited on indium tin oxide electrode displays only one redox couple (at E1/2=0.78V). The films of [(C6H13S)8Pc]2Dy were modified chemically or electrochemically for the detection of reduced NADH in water solution. The modified film in the oxidized ([(C6H13S)8Pc]2Dy)+ form is believed to be reduced to its neutral form on interaction with NADH.</div>
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<AbstractText>Electrochromic properties of spun films of bis[octakis(hexylthio)phthalocyaninato] dysprosium(III) were investigated for determining nicotinamide adenine dinucleotide hydride (NADH) in water solutions. A spin-coated film deposited on indium tin oxide electrode displays only one redox couple (at E1/2=0.78V). The films of [(C6H13S)8Pc]2Dy were modified chemically or electrochemically for the detection of reduced NADH in water solution. The modified film in the oxidized ([(C6H13S)8Pc]2Dy)+ form is believed to be reduced to its neutral form on interaction with NADH.</AbstractText>
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<RefSource>Curr Opin Cell Biol. 2003 Apr;15(2):241-6</RefSource>
<PMID Version="1">12648681</PMID>
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<CommentsCorrections RefType="Cites">
<RefSource>Adv Colloid Interface Sci. 2005 Nov 30;116(1-3):1-11</RefSource>
<PMID Version="1">16083837</PMID>
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<CommentsCorrections RefType="Cites">
<RefSource>Analyst. 2005 Sep;130(9):1232-9</RefSource>
<PMID Version="1">16096667</PMID>
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<CommentsCorrections RefType="Cites">
<RefSource>J Am Chem Soc. 2003 Apr 9;125(14):4014-5</RefSource>
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